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Chapter:

100+ Alkane Solved MCQs

in Pharmaceutical Organic Chemistry 1

These multiple-choice questions (MCQs) are designed to enhance your knowledge and understanding in the following areas: Bachelor of Pharmacy (B. Pharma) , Pharmacy .

Chapters

Chapter: Alkane
51.

Which of the following compound has maximum boiling point……..

A. n-hexane
B. n-pentane
C. 2, 2-dimethyl propane
D. 2-methyl butane
Answer» A. n-hexane
52.

Knocking sound occurs in engine when fuel……….

A. Ignites slowly
B. Ignites rapidly
C. Contains water
D. Is mixed with machine oil
Answer» B. Ignites rapidly
53.

Petroleum is mainly a mixture of………..

A. Alkanes
B. Cyclohexane
C. Benzenoid hydrocarbons
D. Alkenes
Answer» A. Alkanes
54.

Which of the following has maximum boiling point……………

A. iso-octane
B. n-octane
C. 2, 2, 3, 3-tetramethyl butane
D. n-butane
Answer» B. n-octane
55.

Aqueous solution of the following compound on electrolysis gives ethane……….

A. Acetic acid
B. Acetamide
C. Potassium acetate
D. Ethyl acetate
Answer» C. Potassium acetate
56.

Which of the following does not decolourise bromine solution in carbon disulphide………..

A. Acetylene
B. Propene
C. Ethane
D. Propyne
Answer» C. Ethane
57.

Anhydrous sodium acetate on heating with sodalime gives………….

A. Acetic acid
B. Methane
C. Calcium acetate
D. Ethane
Answer» B. Methane
58.

Water gas is………..

A. CO + CO2
B. CO + N2
C. CO + H2
D. CO + N2 + H2
Answer» C. CO + H2
59.

A sample of gasoline contains 81% iso-octane and 19% nheptane. Its octane number will be……..

A. 19
B. 81
C. 100
D. 62
Answer» B. 81
60.

The natural petroleum contains………….

A. Saturated hydrocarbons
B. Cyclic saturated hydrocarbons
C. Compounds of sulphur
D. All of these
Answer» D. All of these
61.

The preparation of ethane by electrolysis of aqueous solution of potassium acetate is called as…….

A. Wurtz reaction
B. Sabatier-Senderen's reaction
C. Kolbe's synthesis
D. Grignard reaction
Answer» C. Kolbe's synthesis
62.

As the number of carbon atoms in a chain increases the boiling point of alkanes……….

A. Increases
B. Decreases
C. Remains same
D. May increase or decrease
Answer» A. Increases
63.

In the fractional distillation of crude petroleum………..

A. Petrol condenses at the bottom of the column
B. The gases condense at the top of the column
C. High boiling constituents condense at the bottom of the column
D. High boiling constituents condense at the top of the column
Answer» C. High boiling constituents condense at the bottom of the column
64.

Which of the following is not an endothermic reaction…………

A. Dehydrogenation
B. Ethane to ethene
C. Combustion of propane
D. Change of chlorine molecule into chlorine atoms
Answer» C. Combustion of propane
65.

Gasoline is the name of ……………

A. Crude oil
B. The gaseous constituents of petroleum
C. The mixture of uncondensed gases produced in the distillation of crude oil
D. The mixture of the residue and gas oil obtained in the distillation of crude oil
Answer» B. The gaseous constituents of petroleum
66.

In the process of cracking……………

A. Organic compounds decompose into their constituent elements
B. Hydrocarbons decompose into carbon and hydrogen
C. High molecular weight organic compounds decompose to give low molecular weight organic compounds
D. Hydrocarbons yield alkyl radicals and hydrogen
Answer» C. High molecular weight organic compounds decompose to give low molecular weight organic compounds
67.

Octane number has 0 value for……….

A. iso-octane
B. n-hexane
C. n-heptane
D. iso-heptane
Answer» C. n-heptane
68.

Dry distillation of sodium propanoate with sodalime gives …………..

A. Propane
B. Propene
C. Ethane
D. Ethene
Answer» C. Ethane
69.

A mixture of propene and methane is obtained by the cracking of…………..

A. 1-butene
B. 2-butene
C. n-butane
D. Isobutane
Answer» C. n-butane
70.

Which of the following fractions of petroleum refining contains kerosene ? (Boiling ranges in o C are given below)

A. 40 – 80
B. 80 - 200
C. 200 - 300
D. Above 300
Answer» C. 200 - 300
71.

On mixing tetraethyl lead to gasoline available at petrol pumps…………..

A. Calorific value of the fuel increases
B. Odour diminishes
C. Less smoke is obtained on combustion
D. Antiknock property of fuel increases
Answer» D. Antiknock property of fuel increases
72.

A liquid hydrocarbon can be converted to gaseous hydrocarbon by…………..

A. Cracking
B. Hydrolysis
C. Oxidation
D. Distillation under reduced pressure
Answer» A. Cracking
73.

The tetrahedral nature of carbon was first given by………….

A. Kekule
B. Le Bell and Van't Hoff
C. Pauling
D. Armstrong and Bayer
Answer» B. Le Bell and Van't Hoff
74.

Formation of alkane by the action of Zn on alkyl halide is called

A. Frankland's reaction
B. Wurtz reaction
C. Cannizzaro reaction
D. Kolbe's reaction
Answer» A. Frankland's reaction
75.

Name the hydrocarbon that is a liquid at STP……….

A. Ethane
B. Propane
C. n-butane
D. n-pentane
Answer» D. n-pentane
76.

Which statement is not true concerning alkanes………..

A. Large number alkanes are soluble in water
B. All alkanes have a lower density than water
C. At room temperature some alkanes are liquids, some solids and some gases
D. All alkanes burn
Answer» A. Large number alkanes are soluble in water
77.

Fischer Tropsch process is used for the manufacture of…………

A. Synthetic petrol
B. Thermosetting plastics
C. Ethanol
D. Benzene
Answer» A. Synthetic petrol
78.

A fuel contains 25 % n-heptane and 75 % iso-octane. Its octane number is……………

A. 50
B. 75
C. 100
D. 25
Answer» B. 75
79.

Sodium ethoxide is a specific reagent for……………

A. Dehydration
B. Dehydrogenation
C. Dehydrohalogenation
D. Dehalogenation
Answer» C. Dehydrohalogenation
80.

Which of the following has highest percentage of hydrogen………..

A. CH4
B. C2H4
C. C6H6
D. C2H2
Answer» A. CH4
81.

What is the molecular formula of the alkane, the 5.6 litre of which weight 11 g at STP……….

A. C6 H14
B. C4H10
C. C3H8
D. C2H6
Answer» C. C3H8
82.

The order of appearance of the following with rising temperature during the refining of crude oil is…..…......

A. Kerosene oil, gasoline, diesel
B. Diesel, gasoline, kerosene oil
C. Gasoline, diesel, kerosene oil
D. Gasoline, kerosene oil, diesel
Answer» D. Gasoline, kerosene oil, diesel
83.

When sodium propionate is heated with soda lime, the main product is…………..

A. Ethane
B. Methane
C. Propane
D. Butane
Answer» A. Ethane
84.

Gasoline is a mixture of alkanes with the number of carbon atoms …………….

A. C3 + C5
B. C5 + C6
C. C6 + C8
D. C7 + C9
Answer» D. C7 + C9
85.

The final product of complete oxidation of hydrocarbons is ………..

A. Acid
B. Aldehyde
C. H2O + CO2
D. Dihydric alcohol
Answer» C. H2O + CO2
86.

Which of the following will have least hindered rotation about carbon-carbon bond…………

A. Ethane
B. Ethylene
C. Acetylene
D. Hexachloroethane
Answer» A. Ethane
87.

How many types of carbon atoms are present in 2, 2, 3trimethylpentane………..

A. One
B. Two
C. Three
D. Four
Answer» D. Four
88.

Which one gives only one monosubstitution product on chlorination………..

A. n-pentane
B. (b) Neopentane
C. (c) Isopentane
D. (d) n-butane
Answer» B. (b) Neopentane
89.

CH4 is formed when………….

A. Sodium acetate is heated with sodalime
B. Iodomethane is reduced
C. Aluminium carbide reacts with water
D. All of these
Answer» D. All of these
90.

Which one of the following compounds does not give addition reactions………………

A. Aldehydes
B. Alkanes
C. Alkenes
D. Alkynes
Answer» B. Alkanes
91.

The most important method of preparation of hydrocarbons of lower carbon number is………….

A. Pyrolysis of higher carbon number hydrocarbons
B. Electrolysis of salts of fatty acids
C. Sabatier and Senderen's reaction
D. Direct synthesis
Answer» A. Pyrolysis of higher carbon number hydrocarbons
92.

The inorganic origin of petroleum is indicated by the fact that…………..

A. Its constituents can be separated by fractional distillation
B. Carbon and hydrocarbon can combine by absorption of solar energy to give hydrocarbons
C. Petroleum contains traces of chlorophyll
D. Oil fields are located with the help of seismograph
Answer» B. Carbon and hydrocarbon can combine by absorption of solar energy to give hydrocarbons
93.

By Wurtz reaction, a mixture of methyliodide and ethyliodide gives………….

A. Butane
B. Ethane
C. Propane
D. A mixture of the above three
Answer» D. A mixture of the above three
94.

Product obtained by nitration of propane is …………….

A. Nitropropane
B. Nitromethane
C. Nitroethane
D. All of these
Answer» D. All of these
95.

Isomerism in saturated hydrocarbons is due to…………..

A. Change in the valence of carbon
B. Change in the ratio of elements in compounds
C. Formation of branches in the chain of C atoms
D. Formation of double bond
Answer» C. Formation of branches in the chain of C atoms
96.

Which of the following is not linked with methane………….

A. Marsh gas
B. Natural gas
C. Producer gas
D. Coal gas
Answer» C. Producer gas
97.

Which of the following has highest octane number…………..

A. n-hexane
B. n-heptane
C. Iso-octane
D. n-heptane and iso-octane mixed in ratio 50 : 50
Answer» C. Iso-octane
98.

A mixture of ethyl iodide and n-propyl iodide is subjected to Wurtz reaction. The hydrocarbon that will not be formed is…………..

A. n-butane
B. n-propane
C. n-pentane
D. n-hexan
Answer» B. n-propane
99.

Most of the hydrocarbons from petroleum are obtained by…………….

A. Fractional distillation
B. Fractional crystallization
C. Vaporization
D. Polymerization
Answer» A. Fractional distillation
100.

Which is the best antiknock compound or Which one of the following substances is used as an antiknock compound ……………

A. Lead tetrachloride
B. Lead acetate
C. Zinc ethyl
D. Tetraethyl lead (TEL)
Answer» D. Tetraethyl lead (TEL)

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