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280+ Pharmaceutical Organic Chemistry 1 Solved MCQs

These multiple-choice questions (MCQs) are designed to enhance your knowledge and understanding in the following areas: Bachelor of Pharmacy (B. Pharma) , Pharmacy .

Chapters

Chapter: Alkane
1.

Which represents an alkane………

A. C5H8
B. C6H8
C. C9H10
D. C7H16
Answer» D. C7H16
2.

The decreasing order of boiling points is ……….

A. n-Pentane > iso-Pentane > neo-Pentane
B. iso-Pentane > n-Pentane > neo-Pentane
C. neo-Pentane > iso-Pentane > n-Pentane
D. n-Pentane > neo-Pentane > iso-Pentane
Answer» A. n-Pentane > iso-Pentane > neo-Pentane
3.

To prepare a pure sample of n-hexane using sodium metal as one reactant, the other reactant will be………

A. n-propyl bromide
B. Ethyl bromide and n-butyl bromide
C. Ethyl chloride and n-butyl chloride
D. Methyl bromide and n -pentyl chloride
Answer» A. n-propyl bromide
4.

In the preparation of Grignard reagent from haloalkane, the metal

A. Mg
B. Zn
C. Li
D. K
Answer» A. Mg
5.

Sodium acetate can be converted to ethane by……….

A. Heating with LiAlH4
B. Electrolysing its aqueous solution
C. Heating with sodalime
D. Heating with calcium acetate
Answer» B. Electrolysing its aqueous solution
6.

Which of the following compounds is used in antiknock compositions to prevent the deposition of oxides of lead on spark plug, combustion chamber and exhaust pipe…….

A. Glycerol
B. Glycol
C. 1, 2-dibromoethane
D. Benzene
Answer» C. 1, 2-dibromoethane
7.

Which of petroleum corresponds to kerosene oil………

A. C15-C18
B. C10 – C12
C. C5 - C9
D. C1 –C9
Answer» B. C10 – C12
8.

In the reaction CH3- Br+ 2Na+ Br-CH3 , the product called ……..

A. Wurtz reaction
B. Aldol condensation
C. Perkin’s reaction
D. Levit reaction
Answer» A. Wurtz reaction
9.

Iodoethane reacts with sodium in the presence of dry ether. The product is……..

A. Pentane
B. Propane
C. Butene
D. Butane
Answer» D. Butane
10.

Which of the following is oxidised by KMnO4

A. Methane
B. Pentane
C. Isobutane
D. Neopentane
Answer» C. Isobutane
11.

The most volatile compound is……….

A. 2, 2-dimethyl propane
B. 2-methyl butane
C. Isobutane
D. n-pentane
Answer» A. 2, 2-dimethyl propane
12.

In Wurtz reaction, the reagent used is………..

A. Na
B. liquid NH3Na
C. ether dry Na
D. alcohol dry Na
Answer» C. ether dry Na
13.

Which of the following has highest octane number…………

A. n-hexane
B. n-heptane
C. n-pentane
D. 2, 2, 4-trimethyl pentane
Answer» D. 2, 2, 4-trimethyl pentane
14.

What is freon-12…….

A. Pesticide
B. Refrigerant
C. Solvent
D. Lubricant
Answer» B. Refrigerant
15.

The petrol having octane number 80 has…………

A. 20% normal heptane + 80% iso-octane
B. 80% normal heptane + 20% iso-octane
C. 20% normal heptane + 80% normal octane
D. 80% normal heptane + 20% normal octane
Answer» A. 20% normal heptane + 80% iso-octane
16.

The shape of methane molecule is………..

A. Linear
B. Trigonal planar
C. Square planar
D. Tetrahedral
Answer» D. Tetrahedral
17.

. Which of the following shows only one brominated compound…………

A. Butene-2
B. 2, 2-dimethylpropane
C. Butyne-1
D. Butanol-3
Answer» B. 2, 2-dimethylpropane
18.

Kerosene is used as fuel because it is………….

A. Less volatile
B. More volatile
C. Cheap
D. Abundantly available
Answer» B. More volatile
19.

Which of the following statements is not true for ethane………….

A. It can be chlorinated with chlorine
B. It can be catalytically hydrogenated
C. When oxidised produces CO2 and H2O
D. It is a homologue of iso-butane
Answer» B. It can be catalytically hydrogenated
20.

Petroleum refining is ……………

A. Distillation of petroleum to get different fractions
B. Obtaining aromatic compounds from aliphatic compounds present in petroleum
C. Cracking of petroleum to get gaseous hydrocarbons
D. Purification of petroleum
Answer» A. Distillation of petroleum to get different fractions
21.

The chemical added to leaded petrol to prevent the deposition of lead in the combustion chamber is……

A. Iso-octane
B. Ethylene dibromide
C. Tetraethyl lead
D. Mercaptan
Answer» B. Ethylene dibromide
22.

In the commercial gasolines, the type of hydrocarbons which are more desirable is………..

A. Branched hydrocarbon
B. Straight-chain hydrocarbon
C. Linear unsaturated hydrocarbon
D. Toluene
Answer» A. Branched hydrocarbon
23.

Which of the following is not formed by the reaction of Cl2 on CH4 in sunlight……….

A. CHCl3
B. CH3Cl
C. CH3CH3
D. CH3CH2CH3
Answer» D. CH3CH2CH3
24.

Which of the following has the highest boiling point………..

A. Neopentane
B. n-butane
C. n-heptane
D. Isobutane
Answer» C. n-heptane
25.

Which gives CH4 when treated with water……..

A. Silicon carbide
B. Calcium carbide
C. Aluminium carbide
D. Iron carbide
Answer» C. Aluminium carbide
26.

Which of the following does not react with PCl5

A. CH3OH
B. CH3COOH
C. CH3CHO
D. C2H6
Answer» D. C2H6
27.

Which of the following compounds is insoluble even in hot concentrated H2SO4………

A. Ethylene
B. Benzene
C. Hexane
D. Aniline
Answer» C. Hexane
28.

A reaction between methyl magnesium bromide and ethyl alcohol gives……….

A. Methane
B. Ethane
C. Propane
D. Butane
Answer» A. Methane
29.

Methane and ethane both can be obtained in single step from …………

A. CH3 I
B. C2H5I
C. CH3OH
D. C2H5OH
Answer» A. CH3 I
30.

Paraffin wax is………..

A. Ester
B. Alcohol
C. Unsaturated hydrocarbon
D. Saturated Hydrocrabon
Answer» D. Saturated Hydrocrabon
31.

The number of possible enantiomeric pairs that can be produced during monochlorination of 2- methylbutane is ……..

A. 2
B. 3
C. 4
D. 1
Answer» A. 2
32.

Petroleum consists mainly of…………

A. Aliphatic hydrocarbons
B. Aromatic hydrocarbons
C. Aliphatic alcohols
D. None of these
Answer» A. Aliphatic hydrocarbons
33.

Petroleum ether can be used as……….

A. Solvent for fat, oil, varnish and rubber
B. As a fuel
C. Both (a) and (b)
D. None of these
Answer» A. Solvent for fat, oil, varnish and rubber
34.

Which of the following are produced from coaltar………..

A. Synthetic dyes
B. Drugs
C. Perfumes
D. All the three
Answer» D. All the three
35.

In alkanes, the bond angle is……..

A. 109.5 o
B. 109 o
C. 120 o
D. 180 o
Answer» A. 109.5 o
36.

In the preparation of alkanes; a concentrated aqueous solution of sodium or potassium salts of saturated carboxylic acid are subjected to………

A. Hydrolysis
B. Oxidation
C. Hydrogenation
D. Electrolysis
Answer» D. Electrolysis
37.

Halogenation of alkanes is an example of………..

A. Electrophilic substitution
B. Nucleophilic substitution
C. Free-radical substitution
D. Oxidation
Answer» C. Free-radical substitution
38.

Propionic acid is subjected to reduction with hydroiodic acid in the presence of a little P, the product formed is…………

A. Ethane
B. Propane
C. Butane
D. None of these
Answer» B. Propane
39.

When ethyl iodide and propyl iodide react with Na in the presence of ether, they form………

A. One alkane
B. Two alkanes
C. Four alkanes
D. Three alkanes
Answer» D. Three alkanes
40.

The alkane that yields two isomeric monobromo derivatives is……………

A. Neopentane
B. Ethane
C. Methane
D. Propane
Answer» D. Propane
41.

Kerosene is a mixture of………….

A. Alkanes
B. Aromatic compounds
C. Alcohols
D. Aliphatic acids
Answer» B. Aromatic compounds
42.

When petroleum is heated the vapours contain mainly………….

A. Kerosene
B. Petroleum ether
C. Diesel
D. Machine oil
Answer» D. Machine oil
43.

Iso-octane is mixed to the petrol………….

A. To precipitate inorganic substances
B. To prevent freezing of petrol
C. To increase boiling point of petrol
D. As an antiknock
Answer» D. As an antiknock
44.

Cyclohexane, a hydrocarbon floats on water because…………

A. It is immiscible with water
B. Its density is low as compared to water
C. It is non-polar substance
D. It is immiscible and lighter than water
Answer» A. It is immiscible with water
45.

Natural gas contains mainly………….

A. Methane
B. n-butane
C. n-octane
D. Mixture of octane
Answer» D. Mixture of octane
46.

Which compound is not inflammable………..

A. CCl4
B. C2H5OH
C. CH4
D. C6H6
Answer» A. CCl4
47.

Propane is obtained from propene, by which of the following methods……….

A. Wurtz reaction
B. Dehydrogenation
C. Frankland reaction
D. Catalytic hydrogenation
Answer» A. Wurtz reaction
48.

LPG is a mixture of………….

A. C6H12+ C6H6
B. C4H10+ C3H8
C. C2H4 + C2H2
D. C2H4 + CH4
Answer» B. C4H10+ C3H8
49.

Carbon black, which is used in making printer's ink, is obtained by decomposition of………….

A. Acetylene
B. Benzene
C. Carbon tetrachloride
D. Methane
Answer» D. Methane
50.

The addition of tetraethyl lead to petrol…………

A. Lowers its octane number
B. Raises its octane number
C. May raise or lower the octane number
D. Has no effect on octane number
Answer» B. Raises its octane number

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