McqMate
These multiple-choice questions (MCQs) are designed to enhance your knowledge and understanding in the following areas: Bachelor of Pharmacy (B. Pharma) , Pharmacy .
Chapters
251. |
The addition of HCN to carbonyl compounds is an example of ………. |
A. | Nucleophilic substitution |
B. | Electrophilic addition |
C. | Nucleophilic addition |
D. | Electrophilic substitution |
Answer» C. Nucleophilic addition |
252. |
Which of the following reagents is used to distinguish acetone and Acetophenone? |
A. | NaHSO3 |
B. | Grignard reagent |
C. | Na2SO4 |
D. | NHCl4 |
Answer» A. NaHSO3 |
253. |
The product formed by the reaction of chlorine with benzaldehyde in the absence of a catalyst is………….. |
A. | Chlorobenzene |
B. | Benzyl chloride |
C. | Benzoyl Chloride |
D. | o –Chlorobenzaldehyde |
Answer» C. Benzoyl Chloride |
254. |
Enol content is highest in………….. |
A. | Acetone |
B. | Acetophenone |
C. | Acetic acid |
D. | Acetyl acetone |
Answer» D. Acetyl acetone |
255. |
Which one of the following reacts with HCN and Tollen's reagent, but is not oxidised by Fehling's solution…………… |
A. | Methanal |
B. | Ethanal |
C. | Benzaldehyde |
D. | Acetone |
Answer» C. Benzaldehyde |
256. |
During reaction of benzaldehyde with alkali one of the product is………… |
A. | Phenol |
B. | Benzyl alcohol |
C. | Benzene |
D. | Benzophenone |
Answer» B. Benzyl alcohol |
257. |
Cannizzaro reaction is given by………… |
A. | HCHO |
B. | CH3COCH3CH |
C. | CH3CHO |
D. | CH3CH2OH |
Answer» A. HCHO |
258. |
When two molecules of acetaldehyde condense in the presence of dilute alkali, it forms…………. |
A. | Acetal |
B. | Sodium formate |
C. | Aldol |
D. | Methylene |
Answer» C. Aldol |
259. |
Acetaldehyde and acetone can be distinguished by…………… |
A. | Molisch test |
B. | Bromoform test |
C. | Solubility in water |
D. | Tollen's test |
Answer» D. Tollen's test |
260. |
Aldehyde turns pink with …………. |
A. | Benedict solution |
B. | Schiff reagent |
C. | Fehling solution |
D. | Tollen's reagent |
Answer» B. Schiff reagent |
261. |
Boiling point of acetone is………….. |
A. | 56oC |
B. | 60 oC |
C. | 100o C |
D. | 90oC |
Answer» A. 56oC |
262. |
The reagent with which both aldehyde and acetone react easily is……………. |
A. | Fehling's reagent |
B. | Grignard reagent |
C. | Schiff's reagent |
D. | Tollen's reagent |
Answer» B. Grignard reagent |
263. |
Acetal is obtained by reacting in the presence of dry HCl and alcohol with………….. |
A. | Aldehyde |
B. | Ketone |
C. | Ether |
D. | Carboxylic acid |
Answer» A. Aldehyde |
264. |
Which of the following is used to detect aldehydes………….. |
A. | Million's test |
B. | Tollen's reagent |
C. | Neutral ferric chloride solution |
D. | Molisch's test |
Answer» B. Tollen's reagent |
265. |
Which of the following aldehydes give red precipitate with Fehling solution ? |
A. | Benzaldehyde |
B. | Salicylaldehyde |
C. | Acetaldehyde |
D. | None of these |
Answer» C. Acetaldehyde |
266. |
Acetaldehyde and Acetone can be distinguished by……….. |
A. | Iododorm test |
B. | Nitroprusside test |
C. | Fehling's solution test |
D. | DNP test |
Answer» C. Fehling's solution test |
267. |
Which of the following will fail to react with potassium dichromate and dilute sulphuric acid…………… |
A. | Ethyl alcohol (ethanol) |
B. | Acetaldehyde (ethanal) |
C. | Secondary propyl alcohol (2-propanol) |
D. | Acetone (propanone) |
Answer» D. Acetone (propanone) |
268. |
The key step in cannizzaro’s reaction is the intermolecular shift of ………. |
A. | Proton |
B. | Hydride ion |
C. | Hydronium ion |
D. | Hydrogen bond |
Answer» B. Hydride ion |
269. |
A compound, containing only carbon, hydrogen and oxygen, has a molecular weight of 44. On complete oxidation it is converted into a compound of molecular weight 60. The original compound is ? |
A. | An aldehyde |
B. | An acid |
C. | An alcohol |
D. | an ether |
Answer» A. An aldehyde |
270. |
Which of the following has the most acidic hydrogen? |
A. | 3-hexanone |
B. | 2, 4-hexanedione |
C. | 2, 5-hexanedione |
D. | 2, 3-hexanedione |
Answer» B. 2, 4-hexanedione |
271. |
Which of the following statements regarding chemical properties of acetophenone are wrong……
|
A. | 1 and 2 |
B. | 2 and 4 |
C. | 3 and 4 |
D. | 1 and 3 |
Answer» C. 3 and 4 |
272. |
Which of the following will not give iodoform test ? |
A. | Isopropyl alcohol |
B. | Ethanol |
C. | Ethanal |
D. | Benzyl alcohol |
Answer» D. Benzyl alcohol |
273. |
What is color is Chloral hydrate? |
A. | Yellow |
B. | White |
C. | Colourless |
D. | None |
Answer» C. Colourless |
274. |
Aldol condensation is dose not ocurre between……….. |
A. | Two different ketone |
B. | Two different aldehyde |
C. | An ketone and aldehyde |
D. | An aldehyde and ester |
Answer» D. An aldehyde and ester |
275. |
In which of the following reaction new carbon carbon bond is not formed? |
A. | Cannizzaro reaction |
B. | Friedel craft reaction |
C. | Wurtz reaction |
D. | Aldol condensation |
Answer» A. Cannizzaro reaction |
276. |
Aromatic aldehydes reduce………… |
A. | Tollen’s reagent |
B. | Benedict’s reagent |
C. | Fehling reagent |
D. | All of above |
Answer» A. Tollen’s reagent |
277. |
Cross Cannizzaro reaction is given by……….. |
A. | C6H5CHO |
B. | C6H5CHO |
C. | CH3CHO |
D. | All of above |
Answer» A. C6H5CHO |
278. |
The product formed in aldol condensation is……………. |
A. | Beta hydroxy acid |
B. | Beta hydroxy aldehyde or ketone |
C. | Alpha, beta unsaturated ester |
D. | Alpha, hydroxy aldehyde or ketone |
Answer» B. Beta hydroxy aldehyde or ketone |
279. |
In which type of reaction cyanohydrin formed from acetone? |
A. | Nucleophilic substitution |
B. | Electrophilic substitution |
C. | Nucleophilic addition |
D. | Electrophilic addition |
Answer» C. Nucleophilic addition |
280. |
Which of the following react with water? |
A. | ClCH2CH2Cl |
B. | Cl3CCHO |
C. | CCl4 |
D. | All of above |
Answer» B. Cl3CCHO |
281. |
What is carbonyl group? |
A. | OH |
B. | C=O |
C. | C- O |
D. | None of above |
Answer» B. C=O |
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