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280+ Pharmaceutical Organic Chemistry 1 Solved MCQs

These multiple-choice questions (MCQs) are designed to enhance your knowledge and understanding in the following areas: Bachelor of Pharmacy (B. Pharma) , Pharmacy .

Chapters

Chapter: Alkane
101.

In the dichlorination reaction of propane, mixture of products are obtained. How many isomers, the mixture contains…………

A. 2
B. 3
C. 4
D. 5
Answer» C. 4
102.

Which of the following cycloalkane gives open chain compound, when reacts with bromine………..

A. Cyclopropane
B. Cyclopentane
C. Cyclohexane
D. Cyclo-octane
Answer» A. Cyclopropane
103.

Grignard reagent is not prepared in aqueous medium but prepared; in ether medium because the reagent…………..

A. Reacts with water
B. Is insoluble in water
C. Is highly reactive in ether
D. Becomes inactive in water
Answer» A. Reacts with water
104.

A sample of petrol is a mixture of 30% n-heptane and 70% iso-octane. The sample has octane number…………

A. 30
B. 70
C. 15
D. 35
Answer» B. 70
105.

Photochemical chlorination of alkane is initiated by a process of……………

A. Pyrolysis
B. Substitution
C. Cracking
D. Homolysis
Answer» D. Homolysis
106.

A petroleum fraction having boiling range 70-200°C and containing 6-10 carbon atoms per molecule is called………..

A. Natural gas
B. Gas oil
C. Gasoline
D. Kerosene
Answer» C. Gasoline
107.

Pick out the alkane which differs from the other members of the group.

A. 2,2-dimethyl propane
B. Pentane
C. 2-methyl butane
D. 2,2-dimethyl butane
Answer» D. 2,2-dimethyl butane
108.

2-Methylbutane on reacting with bromine in the presence of sunlight gives mainly……..

A. 1-bromo-2-methylbutane
B. 2-bromo-2-methylbutane
C. 2-bromo-3-methylbutane
D. 1-bromo-3-methylbutane
Answer» B. 2-bromo-2-methylbutane
109.

Of the five isomeric hexanes, the isomer which can give two monochlorinated compounds is…………..

A. n-hexane
B. 2, 3-dimethylbutane
C. 2, 2-dimethylbutane
D. 2-methylpentane
Answer» B. 2, 3-dimethylbutane
Chapter: Alcohol
110.

Which group is present on alcohol.

A. OH
B. C=O
C. CHO
D. NO2
Answer» A. OH
111.

Which suffix attached in alcohol.

A. En
B. Ol
C. Ene
D. Hyde
Answer» B. Ol
112.

Butane-2-ol is …….

A. Primary alcohol
B. Secondary alcohol
C. Tertiary alcohol
D. Aldehyde
Answer» B. Secondary alcohol
113.

Pentanol is a……..

A. Primary alcohol
B. Secondary alcohol
C. Tertiary alcohol
D. None of these
Answer» C. Tertiary alcohol
114.

Glycerol is a……

A. Primary alcohol
B. Monohydric alcohol
C. Secondary alcohol
D. Trihydric alcohol
Answer» D. Trihydric alcohol
115.

Which is primary alcohol…….

A. Butane-2-ol
B. Butane-1-ol
C. Propane-2-ol
D. Isopropyl alcohol
Answer» B. Butane-1-ol
116.

General formula of primary alcohol is …….

A. CHOH
B. COH
C. CH2OH
D. COHOH
Answer» C. CH2OH
117.

The characteristic grouping of secondary alcohols is…….

A. CHOH
B. COH
C. CH2OH
D. COHOH
Answer» A. CHOH
118.

Which of the following are isomers…….

A. Methyl alcohol and dimethyl ether
B. Ethyl alcohol and dimethyl ether
C. Acetone and acetaldehyde
D. Propionic acid and propanone
Answer» B. Ethyl alcohol and dimethyl ether
119.

The compound HOH2C - CH2OH is…….

A. Ethane glycol
B. Ethylene glycol
C. Ethylidene alcohol
D. Dimethyl alcohol
Answer» B. Ethylene glycol
120.

Methylated spirit is……..

A. Methanol
B. Methanol + ethanol
C. Methanoic acid
D. Methanamide
Answer» B. Methanol + ethanol
121.

Absolute alcohol is…….

A. 100% pure ethanol
B. 95% alcohol + 5% H2O
C. Ethanol + water + phenol
D. 95% ethanol + 5% methanol.
Answer» A. 100% pure ethanol
122.

Which of the following is dihydric alcohol …….

A. Glycerol
B. Ethylene glycol
C. Catechol
D. Resorcinol
Answer» B. Ethylene glycol
123.

Wood spirit is known as ………

A. Methanol
B. Ethanol
C. Acetone
D. Benzene
Answer» A. Methanol
124.

Which one of the following will produce a primary alcohol by reacting with CH3MgI……..

A. Acetone
B. Methyl cyanide
C. Ethylene oxide
D. Ethyl acetate
Answer» C. Ethylene oxide
125.

The fermentation of starch to give alcohol occurs mainly with the help of ………

A. O2
B. Air
C. CO2
D. Enzymes
Answer» D. Enzymes
126.

Ethanol is prepared industrially by………

A. Hydration of ethylene
B. Fermentation of sugars
C. Both the above
D. None of these
Answer» C. Both the above
127.

Ethyl alcohol is industrially prepared from ethylene by……..

A. Permanganate oxidation
B. Catalytic reduction
C. Absorbing in H2SO4 followed by hydrolysis
D. Fermentation
Answer» C. Absorbing in H2SO4 followed by hydrolysis
128.

Coconut oil upon alkaline hydrolysis gives…….

A. Glycol
B. Alcohol
C. Glycerol
D. Ethylene oxide
Answer» C. Glycerol
129.

Which enzyme converts glucose and fructose both into ethanol……..

A. Diastase
B. Invertase
C. Zymase
D. Maltase
Answer» C. Zymase
130.

Primary alcohols can be obtained from the reaction of the RMgX……

A. CO2
B. HCHO
C. CH3 CHO
D. H2O
Answer» B. HCHO
131.

Formaldehyde gives an additive product with methyl magnesium iodide which on aqueous hydrolysis gives …..

A. Isopropyl alcohol
B. Ethyl alcohol
C. Methyl alcohol
D. Propyl alcohol
Answer» B. Ethyl alcohol
132.

Benzyl alcohol is obtained from benzaldehyde by…..

A. Fittig's reaction
B. Cannizaro's reaction
C. Kolbe's reaction
D. Wurtz's reaction
Answer» B. Cannizaro's reaction
133.

The product of reduction of benzaldehyde is …..

A. Benzoic acid
B. Benzyl alcohol
C. Benzene
D. Catechol
Answer» B. Benzyl alcohol
134.

Alkenes convert into alcohols by……

A. Hydrolysis by dil. Sulphuric acid
B. Hydration of alkene by alkaline KMnO4
C. Hydrolysis by water vapours and conc. Sulphuric acid
D. Hydration of alkene by aqueous KOH
Answer» B. Hydration of alkene by alkaline KMnO4
135.

Acetic acid and CH3 are obtained on large scale by destructive distillation of…..

A. Wood
B. Coal
C. Turpentine
D. Crude oil
Answer» A. Wood
136.

Acid catalyzed hydration of alkenes except ethene leads to the formation of ……

A. Primary alcohol
B. Secondary or tertiary alcohol
C. Mixture of primary and secondary alcohols
D. Mixture of secondary and tertiary alcohols
Answer» B. Secondary or tertiary alcohol
137.

The boiling point of alcohol are …. than corresponding thiols.

A. More
B. Same
C. Either of these
D. Less
Answer» A. More
138.

Methyl alcohol can be distinguished from ethyl alcohol using ……

A. Fehling solution
B. Schiff's reagent
C. Sodium hydroxide and iodine
D. Phthalein fusion test
Answer» C. Sodium hydroxide and iodine
139.

A compound X with molecular formula C3H8O can be oxidised to a compound Y with the molecular formula C3H6O2 X is most likely to be …..

A. Primary alcohol
B. Secondary alcohol
C. Aldehyde
D. Ketone
Answer» A. Primary alcohol
140.

On heating glycerol with conc. H2SO4 a compound is obtained which has a bad odour. The compound is…..

A. Glycerol sulphate
B. Acrolein
C. Formic acid
D. Allyl alcohol
Answer» B. Acrolein
141.

Isopropyl alcohol on oxidation forms……

A. Acetone
B. Ether
C. Ethylene
D. Acetaldehyde
Answer» A. Acetone
142.

. The alcohol that produces turbidity immediately with ZnCl2 + conc. HCl at room temperature…..

A. 1-hydroxybutane
B. 2-hydroxybutane
C. 2-hydroxy-2-methylpropane
D. 1-hydroxy-2-methylpropane
Answer» C. 2-hydroxy-2-methylpropane
143.

The reagent which easily reacts with ethanol and propanol is……

A. Fehling solution
B. Grignard reagent
C. Schiff's reagent
D. Tollen's reagent
Answer» B. Grignard reagent
144.

Propene is the product obtained by dehydrogenation of …….

A. 2-propanol
B. 1-propanol
C. Propanal
D. n -propyl alcohol
Answer» A. 2-propanol
145.

Which of the following statements is correct…..

A. Phenol is less acidic than ethyl alcohol
B. Phenol is more acidic than ethyl alcohol
C. Phenol is more acidic than carboxylic acid
D. Phenol is more acidic than carbonic acid
Answer» B. Phenol is more acidic than ethyl alcohol
146.

Boiling point of alcohol is comparatively higher than that corresponding alkane due to…….

A. Intermolecular hydrogen bonding
B. Intramolecular hydrogen bonding
C. Volatile nature
D. None of these
Answer» A. Intermolecular hydrogen bonding
147.

. The reaction of C2H5OH with H2SO4 does not give ……

A. Ethylene
B. Diethyl ether
C. Acetylene
D. Ethyl hydrogen sulphate
Answer» C. Acetylene
148.

In reaction of alcohols with alkali metal, acid etc. which of the following alcohol will react fastest….

A. Secondary
B. Tertiary
C. Primary
D. All equal
Answer» C. Primary
149.

Order of reactivity of alcohols towards sodium metal is ……

A. Pri > Sec > Ter
B. Pri > Sec <Ter
C. Pri < Sec > Ter
D. Pri < Sec < Ter
Answer» D. Pri < Sec < Ter
150.

The -OH group of methyl alcohol cannot be replaced by chlorine by the action of……

A. Chlorine
B. Hydrogen chloride
C. Phosphorus trichloride
D. Phosphorus pentachloride
Answer» A. Chlorine

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