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280+ Pharmaceutical Organic Chemistry 1 Solved MCQs

These multiple-choice questions (MCQs) are designed to enhance your knowledge and understanding in the following areas: Bachelor of Pharmacy (B. Pharma) , Pharmacy .

Chapters

Chapter: Alcohol
151.

Which compound has the highest boiling point……

A. Acetone
B. Diethyl ether
C. Methanol
D. Ethanol
Answer» D. Ethanol
152.

Dehydration of ethanol gives……

A. Acetic acid
B. Ethane
C. Ethylene
D. Acetylene
Answer» C. Ethylene
153.

Absolute ethanol cannot be obtained by simple fraction of a solution of ethanol and water because…..

A. Their B.P.'s are very nearer
B. Ethanol remains dissolved in water
C. They form a constant boiling mixture
D. Ethanol molecules are solvated
Answer» C. They form a constant boiling mixture
154.

In esterification, the reactivity of alcohols is ……

A. 1° > 2° > 3°
B. 3° > 2° > 1°
C. Same in all cases
D. None of these
Answer» A. 1° > 2° > 3°
155.

Methanol and ethanol are distinguished by the…….

A. Action of HCl
B. Iodoform test
C. Solubility in water
D. Sodium
Answer» B. Iodoform test
156.

Ethyl alcohol exhibits acidic character on reacting with…….

A. Acetic acid
B. Sodium metal
C. Hydrogen iodide
D. Acidic potassium dichromate
Answer» B. Sodium metal
157.

Which of the following is not characteristic of alcohols……

A. They are lighter than water
B. Their boiling points rise fairly uniformly with increasing molecular weight
C. Lower members are insoluble in water and organic solvents but solubility regularly increases with molecular weight
D. Lower members have pleasant smell and burning taste, while higher members are odourless and tasteless
Answer» C. Lower members are insoluble in water and organic solvents but solubility regularly increases with molecular weight
158.

By means of calcium chloride which of following can be dried……

A. Methanol
B. Ethanol
C. Both (a) and (b)
D. None of these
Answer» D. None of these
159.

Dimethyl ether and ethyl alcohol are …..

A. Branched isomer
B. Position isomer
C. Functional isomer
D. Tautomer
Answer» C. Functional isomer
160.

The process of manufacture of absolute alcohol from rectified spirit is…….

A. Fractional distillation
B. Steam distillation
C. Azeotropic distillation
D. Vacuum distillation
Answer» C. Azeotropic distillation
161.

When ethyl alcohol reacts with acetic acid, the products formed are…..

A. Sodium ethoxide + hydrogen
B. Ethyl acetate + water
C. Ethyl acetate + soap
D. Ethyl alcohol + water
Answer» B. Ethyl acetate + water
162.

Methanol and ethanol are miscible in water due to…..

A. Covalent character
B. Hydrogen bonding character
C. Oxygen bonding character
D. None of these
Answer» B. Hydrogen bonding character
163.

Which of the following is most soluble in water……

A. Normal butyl alcohol
B. Isobutyl alcohol
C. Tertiary butyl alcohol
D. Secondary butyl alcohol
Answer» C. Tertiary butyl alcohol
164.

If ethanol dissolves in water, then which of the following would be done……

A. Absorption of heat and contraction in volume
B. Emission of heat and contraction in volume
C. Absorption of heat and increase in volume
D. Emission of heat and increase in volume
Answer» B. Emission of heat and contraction in volume
165.

When rectified spirit and benzene are distilled together, the first fraction obtained is……

A. A ternary azeotrope
B. Absolute alcohol
C. A binary azeotrope
D. Denatured spirit
Answer» A. A ternary azeotrope
166.

Alcohols combine with acetylene in the presence of mercury compounds as catalyst to form…….

A. Acetals
B. Xanthates
C. Vinyl ethers
D. None of the above
Answer» A. Acetals
167.

The boiling point of methanol is greater than that of methyl thiol because

A. There is intramolecular hydrogen bonding in methanol and intermolecular hydrogen bonding in methyl thiol
B. There is intermolecular hydrogen bonding in methanol and no hydrogen bonding in methyl thiol
C. There is no hydrogen bonding in methanol and intermolecular hydrogen bonding in methyl thiol
D. There is intramolecular hydrogen bonding in methanol and no hydrogen bonding in methyl thiol
Answer» B. There is intermolecular hydrogen bonding in methanol and no hydrogen bonding in methyl thiol
168.

At 530 K , glycerol reacts with oxalic acid to produce …….

A. Allyl alcohol
B. Formic acid
C. Glyceraldehyde
D. Glycerol monooxalate
Answer» A. Allyl alcohol
169.

With anhydrous zinc chloride, ethylene glycol gives…….

A. Formaldehyde
B. Acetylene
C. Acetaldehyde
D. Acetone
Answer» C. Acetaldehyde
170.

Amongst the following, HBr reacts fastest with…….

A. Propane-1-ol
B. Propane-2-ol
C. 2-methyl propane-1-ol
D. 2-methyl propane-2-ol
Answer» D. 2-methyl propane-2-ol
171.

Which alcohol reacts with fatty acids to form fats…….

A. Ethanol
B. Glycerol
C. Methanol
D. Isopropanol
Answer» B. Glycerol
172.

Which will dehydrate easily…….

A. 3-methyl-2-butanol
B. Ethyl alcohol
C. 2-methyl propane-2-ol
D. 2-methyl butanol-2
Answer» D. 2-methyl butanol-2
173.

On reaction with hot conc. H2SO4 which one of the following compounds loses a molecule of water….

A. CH3COCH3
B. CH3COOH
C. CH3OCH3
D. CH3CH2OH
Answer» D. CH3CH2OH
174.

C2H5OH can be differentiated from CH3OH by…..

A. Reaction with HCl
B. Reaction with 3 NH
C. By iodoform test
D. By solubility in water
Answer» C. By iodoform test
175.

Glycerol is used in the manufacture of

A. Dynamite
B. Varnish
C. Paints
D. Soft drinks
Answer» A. Dynamite
176.

Rectified spirit is a mixture of ……….

A. 95% ethyl alcohol + 5% water
B. 94% ethyl alcohol + 4.53% water
C. 94.4% ethyl alcohol + 5.43 % water
D. 95.57% ethyl alcohol + 4.43% water
Answer» D. 95.57% ethyl alcohol + 4.43% water
177.

Glycerol as a triester present in …….

A. Petroleum
B. Kerosene
C. Vegetable oil and fat
D. Naphtha
Answer» C. Vegetable oil and fat
178.

: Power alcohol is ……

A. An alcohol of 95% purity
B. A mixture of petrol hydrocarbons and ethanol
C. Rectified spirit
D. A mixture of methanol and ethanol
Answer» B. A mixture of petrol hydrocarbons and ethanol
179.

: In cold countries ethylene glycol is added to water in the radiators to

A. Bring down the specific heat of water
B. Lower the viscosity
C. Reduce the viscosity
D. Make water a better lubricant
Answer» A. Bring down the specific heat of water
180.

Alcoholic fermentation is brought about by the action of

A. CO2
B. O2
C. Invertase
D. Yeast
Answer» D. Yeast
181.

Methyl alcohol is toxic. The reason assigned is………

A. It stops respiratory track
B. It reacts with nitrogen and forms CN in the lungs
C. It increases CO2 content in the blood
D. It is a reduction product of formaldehyde
Answer» B. It reacts with nitrogen and forms CN in the lungs
182.

Glycerol is used……..

A. As a sweetening agent
B. In the manufacture of good quality soap
C. In the manufacture of nitro glycerine
D. In all of these
Answer» D. In all of these
183.

Glycerol is not used in which of following cases…….

A. Explosive making
B. Shaving soap making
C. As an antifreeze for water
D. As an antiseptic agent
Answer» D. As an antiseptic agent
184.

Liquor poisoning is due to …….

A. Presence of bad compound in liquor
B. Presence of methyl alcohol
C. Presence of ethyl alcohol
D. Presence of carbonic acid
Answer» B. Presence of methyl alcohol
185.

In order to make alcohol undrinkable pyridine and methanol are added to it. The resulting alcohol is called ………

A. Power alcohol
B. Proof spirit
C. Denatured spirit
D. Poison alcohol
Answer» C. Denatured spirit
186.

Wine (alcoholic beverages) contains ………

A. CH3OH
B. Glycerol
C. C2H5OH
D. 2-propanol
Answer» C. C2H5OH
187.

Which is used as an antifreeze…….

A. Glycol
B. Ethyl alcohol
C. Water
D. Methanol
Answer» A. Glycol
Chapter: Aldehydes and Ketones
188.

In aldehydes and ketones, carbon of carbonyl group is………..

A. 3 sp hybridised
B. 2 sp hybridised
C. sp hybridised
D. Unhybridised
Answer» B. 2 sp hybridised
189.

Aldehydes are isomeric with………..

A. Ketones
B. Ethers
C. Alcohols
D. Fatty acids
Answer» A. Ketones
190.

Which of the following compounds does not contain an -OH group………..

A. Phenol
B. Carboxylic acid
C. Aldehydes
D. Alcohols
Answer» C. Aldehydes
191.

IUPAC name of CH3COCH3 is………..

A. Acetone
B. 2-propanone
C. Dimethyl ketone
D. Propanal
Answer» B. 2-propanone
192.

Which of the following types of isomerism is shown by Pentanone.

A. Chain isomerism
B. Position isomerism
C. Functional isomerism
D. All of these
Answer» D. All of these
193.

IUPAC name of CHO CCl3 is…………..

A. Chloral
B. Trichloro acetaldehyde
C. 1, 1, 1-trichloroethanal
D. 2, 2, 2-trichloroethanal
Answer» D. 2, 2, 2-trichloroethanal
194.

Which of the following is a mixed ketone ………..

A. Pentanone
B. Acetophenone
C. Benzophenone
D. Butanone
Answer» A. Pentanone
195.

Chloral is………..

A. CCl3CHO
B. CCl3COCCH3
C. CCl3COCCl3
D. CCl3CH2OH
Answer» C. CCl3COCCl3
196.

Carbonyl compounds are usually ……………

A. Ethers, aldehydes, ketones and carboxylic acids
B. Aldehydes, ketones and carboxylic acids
C. Aldehydes and ketones
D. Carboxylic acids
Answer» C. Aldehydes and ketones
197.

Acetone and acetaldehyde are …………..

A. Position isomers
B. Functional isomers
C. Not isomers
D. Chain isomers
Answer» C. Not isomers
198.

Which of the aldehyde is most reactive ?

A. C6H5CHO
B. CH3CHO
C. HCHO
D. All the equally reactive
Answer» D. All the equally reactive
199.

Acetophenone is prepared from

A. Rosenmund reaction
B. Sandmayer reaction
C. Wurtz reaction
D. Friedel craft reaction
Answer» D. Friedel craft reaction
200.

Which one of the following compounds is prepared in the laboratory from benzene by a substitution reaction………

A. Glyoxal
B. Cyclohexane
C. Acetophenone
D. Hexabromo cyclohexane
Answer» C. Acetophenone

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