McqMate
These multiple-choice questions (MCQs) are designed to enhance your knowledge and understanding in the following areas: Bachelor of Pharmacy (B. Pharma) , Pharmacy .
Chapters
151. |
Which compound has the highest boiling point…… |
A. | Acetone |
B. | Diethyl ether |
C. | Methanol |
D. | Ethanol |
Answer» D. Ethanol |
152. |
Dehydration of ethanol gives…… |
A. | Acetic acid |
B. | Ethane |
C. | Ethylene |
D. | Acetylene |
Answer» C. Ethylene |
153. |
Absolute ethanol cannot be obtained by simple fraction of a solution of ethanol and water because….. |
A. | Their B.P.'s are very nearer |
B. | Ethanol remains dissolved in water |
C. | They form a constant boiling mixture |
D. | Ethanol molecules are solvated |
Answer» C. They form a constant boiling mixture |
154. |
In esterification, the reactivity of alcohols is …… |
A. | 1° > 2° > 3° |
B. | 3° > 2° > 1° |
C. | Same in all cases |
D. | None of these |
Answer» A. 1° > 2° > 3° |
155. |
Methanol and ethanol are distinguished by the……. |
A. | Action of HCl |
B. | Iodoform test |
C. | Solubility in water |
D. | Sodium |
Answer» B. Iodoform test |
156. |
Ethyl alcohol exhibits acidic character on reacting with……. |
A. | Acetic acid |
B. | Sodium metal |
C. | Hydrogen iodide |
D. | Acidic potassium dichromate |
Answer» B. Sodium metal |
157. |
Which of the following is not characteristic of alcohols…… |
A. | They are lighter than water |
B. | Their boiling points rise fairly uniformly with increasing molecular weight |
C. | Lower members are insoluble in water and organic solvents but solubility regularly increases with molecular weight |
D. | Lower members have pleasant smell and burning taste, while higher members are odourless and tasteless |
Answer» C. Lower members are insoluble in water and organic solvents but solubility regularly increases with molecular weight |
158. |
By means of calcium chloride which of following can be dried…… |
A. | Methanol |
B. | Ethanol |
C. | Both (a) and (b) |
D. | None of these |
Answer» D. None of these |
159. |
Dimethyl ether and ethyl alcohol are ….. |
A. | Branched isomer |
B. | Position isomer |
C. | Functional isomer |
D. | Tautomer |
Answer» C. Functional isomer |
160. |
The process of manufacture of absolute alcohol from rectified spirit is……. |
A. | Fractional distillation |
B. | Steam distillation |
C. | Azeotropic distillation |
D. | Vacuum distillation |
Answer» C. Azeotropic distillation |
161. |
When ethyl alcohol reacts with acetic acid, the products formed are….. |
A. | Sodium ethoxide + hydrogen |
B. | Ethyl acetate + water |
C. | Ethyl acetate + soap |
D. | Ethyl alcohol + water |
Answer» B. Ethyl acetate + water |
162. |
Methanol and ethanol are miscible in water due to….. |
A. | Covalent character |
B. | Hydrogen bonding character |
C. | Oxygen bonding character |
D. | None of these |
Answer» B. Hydrogen bonding character |
163. |
Which of the following is most soluble in water…… |
A. | Normal butyl alcohol |
B. | Isobutyl alcohol |
C. | Tertiary butyl alcohol |
D. | Secondary butyl alcohol |
Answer» C. Tertiary butyl alcohol |
164. |
If ethanol dissolves in water, then which of the following would be done…… |
A. | Absorption of heat and contraction in volume |
B. | Emission of heat and contraction in volume |
C. | Absorption of heat and increase in volume |
D. | Emission of heat and increase in volume |
Answer» B. Emission of heat and contraction in volume |
165. |
When rectified spirit and benzene are distilled together, the first fraction obtained is…… |
A. | A ternary azeotrope |
B. | Absolute alcohol |
C. | A binary azeotrope |
D. | Denatured spirit |
Answer» A. A ternary azeotrope |
166. |
Alcohols combine with acetylene in the presence of mercury compounds as catalyst to form……. |
A. | Acetals |
B. | Xanthates |
C. | Vinyl ethers |
D. | None of the above |
Answer» A. Acetals |
167. |
The boiling point of methanol is greater than that of methyl thiol because |
A. | There is intramolecular hydrogen bonding in methanol and intermolecular hydrogen bonding in methyl thiol |
B. | There is intermolecular hydrogen bonding in methanol and no hydrogen bonding in methyl thiol |
C. | There is no hydrogen bonding in methanol and intermolecular hydrogen bonding in methyl thiol |
D. | There is intramolecular hydrogen bonding in methanol and no hydrogen bonding in methyl thiol |
Answer» B. There is intermolecular hydrogen bonding in methanol and no hydrogen bonding in methyl thiol |
168. |
At 530 K , glycerol reacts with oxalic acid to produce ……. |
A. | Allyl alcohol |
B. | Formic acid |
C. | Glyceraldehyde |
D. | Glycerol monooxalate |
Answer» A. Allyl alcohol |
169. |
With anhydrous zinc chloride, ethylene glycol gives……. |
A. | Formaldehyde |
B. | Acetylene |
C. | Acetaldehyde |
D. | Acetone |
Answer» C. Acetaldehyde |
170. |
Amongst the following, HBr reacts fastest with……. |
A. | Propane-1-ol |
B. | Propane-2-ol |
C. | 2-methyl propane-1-ol |
D. | 2-methyl propane-2-ol |
Answer» D. 2-methyl propane-2-ol |
171. |
Which alcohol reacts with fatty acids to form fats……. |
A. | Ethanol |
B. | Glycerol |
C. | Methanol |
D. | Isopropanol |
Answer» B. Glycerol |
172. |
Which will dehydrate easily……. |
A. | 3-methyl-2-butanol |
B. | Ethyl alcohol |
C. | 2-methyl propane-2-ol |
D. | 2-methyl butanol-2 |
Answer» D. 2-methyl butanol-2 |
173. |
On reaction with hot conc. H2SO4 which one of the following compounds loses a molecule of water…. |
A. | CH3COCH3 |
B. | CH3COOH |
C. | CH3OCH3 |
D. | CH3CH2OH |
Answer» D. CH3CH2OH |
174. |
C2H5OH can be differentiated from CH3OH by….. |
A. | Reaction with HCl |
B. | Reaction with 3 NH |
C. | By iodoform test |
D. | By solubility in water |
Answer» C. By iodoform test |
175. |
Glycerol is used in the manufacture of |
A. | Dynamite |
B. | Varnish |
C. | Paints |
D. | Soft drinks |
Answer» A. Dynamite |
176. |
Rectified spirit is a mixture of ………. |
A. | 95% ethyl alcohol + 5% water |
B. | 94% ethyl alcohol + 4.53% water |
C. | 94.4% ethyl alcohol + 5.43 % water |
D. | 95.57% ethyl alcohol + 4.43% water |
Answer» D. 95.57% ethyl alcohol + 4.43% water |
177. |
Glycerol as a triester present in ……. |
A. | Petroleum |
B. | Kerosene |
C. | Vegetable oil and fat |
D. | Naphtha |
Answer» C. Vegetable oil and fat |
178. |
: Power alcohol is …… |
A. | An alcohol of 95% purity |
B. | A mixture of petrol hydrocarbons and ethanol |
C. | Rectified spirit |
D. | A mixture of methanol and ethanol |
Answer» B. A mixture of petrol hydrocarbons and ethanol |
179. |
: In cold countries ethylene glycol is added to water in the radiators to |
A. | Bring down the specific heat of water |
B. | Lower the viscosity |
C. | Reduce the viscosity |
D. | Make water a better lubricant |
Answer» A. Bring down the specific heat of water |
180. |
Alcoholic fermentation is brought about by the action of |
A. | CO2 |
B. | O2 |
C. | Invertase |
D. | Yeast |
Answer» D. Yeast |
181. |
Methyl alcohol is toxic. The reason assigned is……… |
A. | It stops respiratory track |
B. | It reacts with nitrogen and forms CN in the lungs |
C. | It increases CO2 content in the blood |
D. | It is a reduction product of formaldehyde |
Answer» B. It reacts with nitrogen and forms CN in the lungs |
182. |
Glycerol is used…….. |
A. | As a sweetening agent |
B. | In the manufacture of good quality soap |
C. | In the manufacture of nitro glycerine |
D. | In all of these |
Answer» D. In all of these |
183. |
Glycerol is not used in which of following cases……. |
A. | Explosive making |
B. | Shaving soap making |
C. | As an antifreeze for water |
D. | As an antiseptic agent |
Answer» D. As an antiseptic agent |
184. |
Liquor poisoning is due to ……. |
A. | Presence of bad compound in liquor |
B. | Presence of methyl alcohol |
C. | Presence of ethyl alcohol |
D. | Presence of carbonic acid |
Answer» B. Presence of methyl alcohol |
185. |
In order to make alcohol undrinkable pyridine and methanol are added to it. The resulting alcohol is called ……… |
A. | Power alcohol |
B. | Proof spirit |
C. | Denatured spirit |
D. | Poison alcohol |
Answer» C. Denatured spirit |
186. |
Wine (alcoholic beverages) contains ……… |
A. | CH3OH |
B. | Glycerol |
C. | C2H5OH |
D. | 2-propanol |
Answer» C. C2H5OH |
187. |
Which is used as an antifreeze……. |
A. | Glycol |
B. | Ethyl alcohol |
C. | Water |
D. | Methanol |
Answer» A. Glycol |
188. |
In aldehydes and ketones, carbon of carbonyl group is……….. |
A. | 3 sp hybridised |
B. | 2 sp hybridised |
C. | sp hybridised |
D. | Unhybridised |
Answer» B. 2 sp hybridised |
189. |
Aldehydes are isomeric with……….. |
A. | Ketones |
B. | Ethers |
C. | Alcohols |
D. | Fatty acids |
Answer» A. Ketones |
190. |
Which of the following compounds does not contain an -OH group……….. |
A. | Phenol |
B. | Carboxylic acid |
C. | Aldehydes |
D. | Alcohols |
Answer» C. Aldehydes |
191. |
IUPAC name of CH3COCH3 is……….. |
A. | Acetone |
B. | 2-propanone |
C. | Dimethyl ketone |
D. | Propanal |
Answer» B. 2-propanone |
192. |
Which of the following types of isomerism is shown by Pentanone. |
A. | Chain isomerism |
B. | Position isomerism |
C. | Functional isomerism |
D. | All of these |
Answer» D. All of these |
193. |
IUPAC name of CHO CCl3 is………….. |
A. | Chloral |
B. | Trichloro acetaldehyde |
C. | 1, 1, 1-trichloroethanal |
D. | 2, 2, 2-trichloroethanal |
Answer» D. 2, 2, 2-trichloroethanal |
194. |
Which of the following is a mixed ketone ……….. |
A. | Pentanone |
B. | Acetophenone |
C. | Benzophenone |
D. | Butanone |
Answer» A. Pentanone |
195. |
Chloral is……….. |
A. | CCl3CHO |
B. | CCl3COCCH3 |
C. | CCl3COCCl3 |
D. | CCl3CH2OH |
Answer» C. CCl3COCCl3 |
196. |
Carbonyl compounds are usually …………… |
A. | Ethers, aldehydes, ketones and carboxylic acids |
B. | Aldehydes, ketones and carboxylic acids |
C. | Aldehydes and ketones |
D. | Carboxylic acids |
Answer» C. Aldehydes and ketones |
197. |
Acetone and acetaldehyde are ………….. |
A. | Position isomers |
B. | Functional isomers |
C. | Not isomers |
D. | Chain isomers |
Answer» C. Not isomers |
198. |
Which of the aldehyde is most reactive ? |
A. | C6H5CHO |
B. | CH3CHO |
C. | HCHO |
D. | All the equally reactive |
Answer» D. All the equally reactive |
199. |
Acetophenone is prepared from |
A. | Rosenmund reaction |
B. | Sandmayer reaction |
C. | Wurtz reaction |
D. | Friedel craft reaction |
Answer» D. Friedel craft reaction |
200. |
Which one of the following compounds is prepared in the laboratory from benzene by a substitution reaction……… |
A. | Glyoxal |
B. | Cyclohexane |
C. | Acetophenone |
D. | Hexabromo cyclohexane |
Answer» C. Acetophenone |
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